Core-Extended Terrylene Tetracarboxdiimide: Synthesis and Chiroptical Characterization

被引：63

作者：

Eversloh, Christian Luetke ^{[1
]}

Liu, Zhihong ^{[2
]}

Mueller, Beate ^{[1
]}

Stangl, Michael ^{[3
]}

Li, Chen ^{[1
]}

Muellen, Klaus ^{[1
]}

机构：

[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

[2] Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China

[3] Johannes Gutenberg Univ Mainz, Inst Pharm & Biochem, D-55128 Mainz, Germany

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 20期

关键词：

PERYLENE BISIMIDES; RESOLUTION;

D O I：

10.1021/ol202254c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The novel 1,16:6,7:8,9:14,15-tetranaphthoterrylene tetracarboxdiimide was synthesized via a straightforward route, yielding optically active atropisomers with a high racemization barrier. Absorption, fluorescence, and circular dichroism measurements revealed high absorption coefficients and fluorescence quantum yields and enabled the stereochemical assignment in combination with quantum mechanical calculations.

引用

页码：5528 / 5531

页数：4

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