A Planar Small Molecule with Dithienosilole Core for High Efficiency Solution-Processed Organic Photovoltaic Cells

被引：200

作者：

Zhou, Jiaoyan

Wan, Xiangjian

Liu, Yongsheng

Long, Guankui

Wang, Fei

Li, Zhi

Zuo, Yi

Li, Chenxi

Chen, Yongsheng ^{[1
]}

机构：

[1] Nankai Univ, Key Lab Funct Polymer Mat, Tianjin 300071, Peoples R China

来源：

CHEMISTRY OF MATERIALS | 2011年 / 23卷 / 21期

关键词：

small molecule; organic photovoltaic; solution process; bulk heterojunction; HETEROJUNCTION SOLAR-CELLS; POLYMERS; DONOR; PERFORMANCE; GENERATION; DENSITY; DESIGN; ATOM;

D O I：

10.1021/cm202588h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An electron-withdrawing terminal small molecule with dithienosilole core shows high photovoltaic performance. The DCAO3TSi:PC61BM based solar cell exhibits a power conversion efficiency of 5.84%, with an open circuit voltage (Voc) of 0.80 V, a short-circuit current density (Jsc) of 11.51 mAcm2, and a high fill factor (FF>) of 0.64 the best so far for a solution-processed small molecule based solar cell. © 2011 American Chemical Society.

引用

收藏

页码：4666 / 4668

页数：3

相关论文

共 44 条

[1] Dithienogermole As a Fused Electron Donor in Bulk Heterojunction Solar Cells [J].

Amb, Chad M. ;

Chen, Song ;

Graham, Kenneth R. ;

Subbiah, Jegadesan ;

Small, Cephas E. ;

So, Franky ;

Reynolds, John R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (26) :10062-10065

[2] DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE [J].

BECKE, AD .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5648-5652

[3] Tailored merocyanine dyes for solution-processed BHJ solar cells [J].

Buerckstuemmer, Hannah ;

Kronenberg, Nils Michael ;

Gsaenger, Marcel ;

Stolte, Matthias ;

Meerholz, Klaus ;

Wuerthner, Frank .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (02) :240-243

[4] Silicon Atom Substitution Enhances Interchain Packing in a Thiophene-Based Polymer System [J].

Chen, Hsiang-Yu ;

Hou, Jianhui ;

Hayden, Amy E. ;

Yang, Hoichang ;

Houk, K. N. ;

Yang, Yang .

ADVANCED MATERIALS, 2010, 22 (03) :371-+

[5] Polymer solar cells with enhanced open-circuit voltage and efficiency [J].

Chen, Hsiang-Yu ;

Hou, Jianhui ;

Zhang, Shaoqing ;

Liang, Yongye ;

Yang, Guanwen ;

Yang, Yang ;

Yu, Luping ;

Wu, Yue ;

Li, Gang .

NATURE PHOTONICS, 2009, 3 (11) :649-653

[6] Synthesis of Conjugated Polymers for Organic Solar Cell Applications [J].

Cheng, Yen-Ju ;

Yang, Sheng-Hsiung ;

Hsu, Chain-Shu .

CHEMICAL REVIEWS, 2009, 109 (11) :5868-5923

[7] Bulk Heterojunction Solar Cells Using Thieno[3,4-c]pyrrole-4,6-dione and Dithieno[3,2-b:2′,3′-d]silole Copolymer with a Power Conversion Efficiency of 7.3% [J].

Chu, Ta-Ya ;

Lu, Jianping ;

Beaupre, Serge ;

Zhang, Yanguang ;

Pouliot, Jean-Remi ;

Wakim, Salem ;

Zhou, Jiayun ;

Leclerc, Mario ;

Li, Zhao ;

Ding, Jianfu ;

Tao, Ye .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (12) :4250-4253

[8] Dicyanovinyl-Substituted Oligothiophenes: Structure-Property Relationships and Application in Vacuum-Processed Small-Molecule Organic Solar Cells [J].

Fitzner, Roland ;

Reinold, Egon ;

Mishra, Amaresh ;

Mena-Osteritz, Elena ;

Ziehlke, Hannah ;

Koerner, Christian ;

Leo, Karl ;

Riede, Moritz ;

Weil, Matthias ;

Tsaryova, Olga ;

Weiss, Andre ;

Uhrich, Christian ;

Pfeiffer, Martin ;

Baeuerle, Peter .

ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (05) :897-910

[9] Synthesis, Characterization, and Photovoltaic Properties of a Low Band Gap Polymer Based on Silole-Containing Polythiophenes and 2,1,3-Benzothiadiazole [J].

Hou, Jianhui ;

Chen, Hsiang-Yu ;

Zhang, Shaoqing ;

Li, Gang ;

Yang, Yang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (48) :16144-+

[10] Improved Performance of Polymer Bulk Heterojunction Solar Cells Through the Reduction of Phase Separation via Solvent Additives [J].

Hoven, Corey V. ;

Dang, Xuan-Dung ;

Coffin, Robert C. ;

Peet, Jeff ;

Nguyen, Thuc-Quyen ;

Bazan, Guillermo C. .

ADVANCED MATERIALS, 2010, 22 (08) :E63-+

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