Synthesis and electropolymerization of a perylenebisimide-functionalized 3,4-ethylenedioxythiophene (EDOT) derivative

被引：70

作者：

Segura, JL ^{[1
]}

Gómez, R

Reinold, E

Bauerle, P

机构：

[1] Univ Ulm, Dept Organ Chem Organ Mat & Combinatorial Chem 2, D-89081 Ulm, Germany

[2] Univ Complutense Madrid, Fac Quim, Dept Quim Organ, E-28040 Madrid, Spain

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 12期

关键词：

D O I：

10.1021/ol050573m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We have developed a convenient and straightforward procedure for the preparation of functionalized 3,4-ethylenedioxythiophene (EDOT) systems by using a new chloromethyl-EDOT derivative as a versatile synthon. Based on this procedure, novel suitably functionalized perylenetetracarboxylic diimide (PDI) dye derivatives covalently linked to 3,4-ethylenedioxythiophene moieties have been synthesized and electrochemically polymerized to yield a donor-acceptor PENT derivative with an enhanced absorption cross-section.

引用

页码：2345 / 2348

页数：4

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