Trismethimazolylhydroborate (Tm) complexes of ruthenium and manganese

被引：39

作者：

Bailey, PJ ^{[1
]}

Lorono-Gonzales, DJ ^{[1
]}

McCormack, C ^{[1
]}

Parsons, S ^{[1
]}

Price, M ^{[1
]}

机构：

[1] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

INORGANICA CHIMICA ACTA | 2003年 / 354卷

关键词：

ruthenium; manganese; tripodal ligand; C-3; symmetry;

D O I：

10.1016/S0020-1693(03)00180-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A number of new complexes of the tris(methimazolyl)hydroborate (Tm) ligand have been synthesised: [(Tm)RuCl(DMSO)2] (1), [(Tm)Ru(p-cymene)]Cl (2), [(Tm)RuCp] (3) and [(Tm)Mn(CO)(3)] (4). Complexes 2 and 4 have been characterised structurally by X-ray crystallography and a partial crystallographic analysis was obtained for 1. The Tm ligand is found to coordinate as a tripod ligand through its sulphur donors in all complexes except 3, for which there is evidence of bidentate coordination and formation of a 16-electron species. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：61 / 67

页数：7

共 34 条

[1] CHLORO(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM AND HYDRIDO(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM COMPLEXES - ANOMALOUS NMR BEHAVIOR OF C5ME5RUH3PR3 (R = CHME2, CY) [J].

ARLIGUIE, T ;

BORDER, C ;

CHAUDRET, B ;

DEVILLERS, J ;

POILBLANC, R .

ORGANOMETALLICS, 1989, 8 (05) :1308-1314

[2] Hydridotris(thioxotriazolyl)borate (Tt), an ambidentate (N3/S3) tripodal ligand.: X-ray crystal structures of sodium, bismuth(III), tin(IV), and manganese(I) complexes [J].

Bailey, PJ ;

Lanfranchi, M ;

Marchiò, L ;

Parsons, S .

INORGANIC CHEMISTRY, 2001, 40 (19) :5030-5035

[3] The anion of a phenyltris(alkylamino)phosphonium (PhTAP) salt as a chelating ligand: Synthesis and X-ray crystal structure of a 16-electron ruthenium(II) organometallic complex [J].

Bailey, PJ ;

Grant, KJ ;

Parsons, S .

ORGANOMETALLICS, 1998, 17 (04) :551-555

[4] Synthesis and characterization of novel mononuclear cadmium thiolate complexes in a sulfur-rich environment [J].

Bakbak, S ;

Incarvito, CD ;

Rheingold, AL ;

Rabinovich, D .

INORGANIC CHEMISTRY, 2002, 41 (04) :998-+

[5] ARENE RUTHENIUM(II) COMPLEXES FORMED BY DEHYDROGENATION OF CYCLOHEXADIENES WITH RUTHENIUM(III) TRICHLORIDE [J].

BENNETT, MA ;

SMITH, AK .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (02) :233-241

[6]

*BRUK AXS, 2001, BRUK SMART

[7] PREPARATION AND REACTIVITY OF 16-ELECTRON HALF-SANDWICH RUTHENIUM COMPLEXES - X-RAY CRYSTAL-STRUCTURE OF (ETA-5-C5ME5)RU(PPRI3)CL [J].

CAMPION, BK ;

HEYN, RH ;

TILLEY, TD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (04) :278-280

[8]

CANDIERO V, 2002, J CHEM SOC DA, P1465

[9] DICHLOROTETRAKIS(DIMETHYL SULPHOXIDE)RUTHENIUM(II) AND ITS USE AS A SOURCE MATERIAL FOR SOME NEW RUTHENIUM(II) COMPLEXES [J].

EVANS, IP ;

SPENCER, A ;

WILKINSO.G .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (02) :204-209

[10] Rhenium(I) organometallic complexes with novel bis(mercaptoimidazolyl)borates and with hydrotris(mercaptoimidazolyl)borate: chemical and structural studies [J].

Garcia, R ;

Paulo, A ;

Domingos, K ;

Santos, I .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 632 (1-2) :41-48

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