Improving Dielectric Properties of BaTiO3/Ferroelectric Polymer Composites by Employing Surface Hydroxylated BaTiO3 Nanoparticles

被引:389
作者
Zhou, Tao [1 ]
Zha, Jun-Wei [2 ]
Cui, Rui-Yao [3 ]
Fan, Ben-Hui [1 ]
Yuan, Jin-Kai [1 ]
Dang, Zhi-Min [1 ,2 ]
机构
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
[2] Univ Sci & Technol, Sch Chem & Biol Engn, Dept Polymer Sci & Engn, Beijing 100083, Peoples R China
[3] Shandong Polytech Univ, Sch Mat Sci & Engn, Jinan 250353, Peoples R China
关键词
barium titanate; hydroxylation; dielectric property; nanocomposites; CERAMIC COMPOSITE; CONSTANT; MICROSTRUCTURE; PERMITTIVITY; HYBRID;
D O I
10.1021/am200492q
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Dielectric properties of poly(vinylidene fluoride) (PVDF) based nanocomposites filled with surface hydroxylated BaTiO3 (h-BT) nanoparticles we:re reported. The h-BT fillers were prepared from crude BaTiO3 (c-BT) in aqueous solution of H2O2. Results showed that the dielectric properties of the h-BT/PVDF nanocomposites had weaker temperature and frequency dependences than that of c-BT/PVDF nanocomposites. Meanwhile, the h-BT/PVDF composites showed lower loss tangent and higher dielectric strength. It is suggested that the strong interaction between h-BT fillers and PVDF matrix is the main reason for the improved dielectric properties.
引用
收藏
页码:2184 / 2188
页数:5
相关论文
共 17 条
[1]   Ceramic-polymer composites with high dielectric constant [J].
Arbatti, Milind ;
Shan, Xiaobing ;
Cheng, Zhongyang .
ADVANCED MATERIALS, 2007, 19 (10) :1369-+
[2]   Polymer Composite and Nanocomposite Dielectric Materials for Pulse Power Energy Storage [J].
Barber, Peter ;
Balasubramanian, Shiva ;
Anguchamy, Yogesh ;
Gong, Shushan ;
Wibowo, Arief ;
Gao, Hongsheng ;
Ploehn, Harry J. ;
zur Loye, Hans-Conrad .
MATERIALS, 2009, 2 (04) :1697-1733
[3]   An efficient approach to derive hydroxyl groups on the surface of barium titanate nanoparticles to improve its chemical modification ability [J].
Chang, Shinn-Jen ;
Liao, Wei-Sheng ;
Ciou, Ci-Jin ;
Lee, Jyh-Tsung ;
Li, Chia-Chen .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2009, 329 (02) :300-305
[4]   Dielectric relaxations in PVDF/BaTiO3 nanocomposites [J].
Chanmal, C. V. ;
Jog, J. P. .
EXPRESS POLYMER LETTERS, 2008, 2 (04) :294-301
[5]   Advanced Calcium Copper Titanate/Polyimide Functional Hybrid Films with High Dielectric Permittivity [J].
Dang, Zhi-Min ;
Zhou, Tao ;
Yao, Sheng-Hong ;
Yuan, Jin-Kai ;
Zha, Jun-Wei ;
Song, Hong-Tao ;
Li, Jian-Ying ;
Chen, Qiang ;
Yang, Wan-Tai ;
Bai, Jinbo .
ADVANCED MATERIALS, 2009, 21 (20) :2077-2082
[6]   Rescaled temperature dependence of dielectric behavior of ferroelectric polymer composites [J].
Dang, ZM ;
Wang, L ;
Wang, HY ;
Nan, CW ;
Xie, D ;
Yin, Y ;
Tjong, SC .
APPLIED PHYSICS LETTERS, 2005, 86 (17) :1-3
[7]   High Energy Density Nanocomposites Based on Surface-Modified BaTiO3 and a Ferroelectric Polymer [J].
Kim, Philseok ;
Doss, Natalie M. ;
Tillotson, John P. ;
Hotchkiss, Peter J. ;
Pan, Ming-Jen ;
Marder, Seth R. ;
Li, Jiangyu ;
Calame, Jeffery P. ;
Perry, Joseph W. .
ACS NANO, 2009, 3 (09) :2581-2592
[8]   Dielectric properties of 65PMN-35PT/P(VDF-TrFE) 0-3 composites [J].
Lam, KH ;
Chan, HLW ;
Luo, HS ;
Yin, QR ;
Yin, ZW ;
Choy, CL .
MICROELECTRONIC ENGINEERING, 2003, 66 (1-4) :792-797
[9]   Epoxy-based nanocomposites for electrical energy storage. II: Nanocomposites with nanofillers of reactive montmorillonite covalently-bonded with barium titanate [J].
Polizos, G. ;
Tomer, V. ;
Manias, E. ;
Randall, C. A. .
JOURNAL OF APPLIED PHYSICS, 2010, 108 (07)
[10]   High-dielectric-constant silver-epoxy composites as embedded dielectrics [J].
Qi, L ;
Lee, BI ;
Chen, SH ;
Samuels, WD ;
Exarhos, GJ .
ADVANCED MATERIALS, 2005, 17 (14) :1777-+