The first crystallographically established bis-qtpy (qtpy=2,2′:6′,2":6′,2′"-quaterpyridine) metal complex

被引：20

作者：

Dell'Amico, DB

Calderazzo, F

Englert, U

Labella, L

Marchetti, F

机构：

[1] Univ Pisa, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy

[2] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52074 Aachen, Germany

[3] Univ Roma La Sapienza, Dipartimento Ingn Chim Mat Mat Prime & Met, I-00161 Rome, Italy

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 04期

关键词：

D O I：

10.1039/b100360g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first example of a crystallographically established bis-adduct of tridentate 2,2':6',2:6',2"'-quaterpyridine (qtpy) of formula [Fe(qtpy)(2)][ClO4](2) has been obtained by treating an aqueous solution of iron(II) perchlorate with the ligand in the presence of triethylamine.

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页码：357 / 358

页数：2

相关论文

共 24 条

[1] CRYSTAL-STRUCTURE OF BIS(2,2'-6',2''-TERPYRIDINE)IRON(II) BIS(PERCHLORATE) HYDRATE [J].

BAKER, AT ;

GOODWIN, HA .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1985, 38 (01) :207-214

[2] Designing dendrimers based on transition metal complexes. Light-harvesting properties and predetermined redox patterns [J].

Balzani, V ;

Campagna, S ;

Denti, G ;

Juris, A ;

Serroni, S ;

Venturi, M .

ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (01) :26-34

[3] COMPLEXES OF 2,2],2]],2]]]-QUATERPYRIDINE WITH FERROUS + FERRIC IONS [J].

BERGH, A ;

GEORGE, P ;

OFFENHAR.PO ;

HAIGHT, GP .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (MAY) :1533-&

[4]

BULGAK II, 1987, KOORDINATS KHIM, V13, P960

[5] SYNTHESIS, PROPERTIES AND CRYSTAL-STRUCTURES OF IRON-(II) AND IRON-(III) COMPLEXES OF 2,2'/6',2''/6'',2'''-QUATERPYRIDINE [J].

CHE, CM ;

CHAN, CW ;

YANG, SM ;

GUO, CX ;

LEE, CY ;

PENG, SM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (18) :2961-2966

[6] HIGHER OLIGOPYRIDINES AS A STRUCTURAL MOTIF IN METALLOSUPRAMOLECULAR CHEMISTRY [J].

CONSTABLE, EC .

PROGRESS IN INORGANIC CHEMISTRY, VOL 42, 1994, 42 :67-138

[7]

Constable EC, 1999, CHEM-EUR J, V5, P498, DOI 10.1002/(SICI)1521-3765(19990201)5:2<498::AID-CHEM498>3.3.CO

[8]

2-M

[9] THE COORDINATION CHEMISTRY OF 2,2'-6',2''-TERPYRIDINE AND HIGHER OLIGOPYRIDINES [J].

CONSTABLE, EC .

ADVANCES IN INORGANIC CHEMISTRY, 1986, 30 :69-121

[10] A CONVENIENT PREPARATION OF 2,2'-6',2''-6'',2'''-QUATERPYRIDINE - THE CRYSTAL AND MOLECULAR-STRUCTURES OF 2,2'-6',2''-6'',2'''-QUATERPYRIDINE AND BIS(ACETONITRILE)-(2,2'-6',2''-6'',2'''-QUATERPYRIDINE)NICKEL(II) HEXAFLUOROPHOSPHATE ACETONITRILE(1/1) [J].

CONSTABLE, EC ;

ELDER, SM ;

HEALY, J ;

TOCHER, DA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (05) :1669-1674