Effect of the type of ion exchange membrane on performance, ion transport, and pH in biocatalyzed electrolysis of wastewater

被引：165

作者：

Rozendal, R. A. ^{[1
,2
]}

Sleutels, T. H. J. A. ^{[1
,2
]}

Hamelers, H. V. M. ^{[1
]}

Buisman, C. J. N. ^{[1
,2
]}

机构：

[1] Wageningen Univ, Sub Dept Environm Technol, NL-6700 EV Wageningen, Netherlands

[2] Wetsus, Ctr Sustainable Water Technol, NL-8900 CC Leeuwarden, Netherlands

来源：

WATER SCIENCE AND TECHNOLOGY | 2008年 / 57卷 / 11期

关键词：

BEAMR; biocatalyzed electrolysis; hydrogen; ion exchange membrane; MFC; microbial fuel cell;

D O I：

10.2166/wst.2008.043

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Previous studies have shown that the application of cation exchange membranes (CEMs) in bioelectrochemical systems running on wastewater can cause operational problems. In this paper the effect of alternative types of ion exchange membrane is studied in biocatalyzed electrolysis cells. Four types of ion exchange membranes are used: (i) a CEM, (ii) an anion exchange membrane (AEM), (iii) a bipolar membrane (BPM), and (iv) a charge mosaic membrane (CMM). With respect to the electrochemical performance of the four biocatalyzed electrolysis configurations, the ion exchange membranes are rated in the order AEM > CEM > CMM > BPM. However, with respect to the transport numbers for protons and/or hydroxyl ions (t(H/OH)) and the ability to prevent pH increase in the cathode chamber, the ion exchange membranes are rated in the order BPM > AEM > CMM > CEM.

引用

页码：1757 / 1762

页数：6

共 12 条

[1]

Kim BH, 1999, J MICROBIOL BIOTECHN, V9, P127

[2] Power generation using different cation, anion, and ultrafiltration membranes in microbial fuel cells [J].

Kim, Jung Rae ;

Cheng, Shaoan ;

Oh, Sang-Eun ;

Logan, Bruce E. .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2007, 41 (03) :1004-1009

[3] Electrochemically assisted microbial production of hydrogen from acetate [J].

Liu, H ;

Grot, S ;

Logan, BE .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (11) :4317-4320

[4] Microbial fuel cells: Methodology and technology [J].

Logan, Bruce E. ;

Hamelers, Bert ;

Rozendal, Rene A. ;

Schrorder, Uwe ;

Keller, Jurg ;

Freguia, Stefano ;

Aelterman, Peter ;

Verstraete, Willy ;

Rabaey, Korneel .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2006, 40 (17) :5181-5192

[5] Electricity-producing bacterial communities in microbial fuel cells [J].

Logan, Bruce E. ;

Regan, John M. .

TRENDS IN MICROBIOLOGY, 2006, 14 (12) :512-518

[6] Performance of single chamber biocatalyzed electrolysis with different types of ion exchange membranes [J].

Rozendal, Rene A. ;

Hamelers, Hubertus V. M. ;

Molenkmp, Redmar J. ;

Buisman, J. N. .

WATER RESEARCH, 2007, 41 (09) :1984-1994

[7] Effects of membrane cation transport on pH and microbial fuel cell performance [J].

Rozendal, Rene A. ;

Hamelers, Hubertus V. M. ;

Buisman, Cees J. N. .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2006, 40 (17) :5206-5211

[8] Principle and perspectives of hydrogen production through biocatalyzed electrolysis [J].

Rozendal, Rene A. ;

Hamelers, Hubertus V. M. ;

Euverink, Gerrit J. W. ;

Metz, Sybrand J. ;

Buisman, Cees J. N. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2006, 31 (12) :1632-1640

[9] A bipolar membrane combined with ferric iron reduction as an efficient cathode system in microbial fuel cells [J].

Ter Heijne, Annemiek ;

Hamelers, Hubertus V. M. ;

De Wilde, Vinnie ;

Rozendal, Rene A. ;

Buisman, Cees J. N. .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2006, 40 (17) :5200-5205

[10] Ion exchange membranes: State of their development and perspective [J].

Xu, TW .

JOURNAL OF MEMBRANE SCIENCE, 2005, 263 (1-2) :1-29

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