Isoreticular Expansion of Metal-Organic Frameworks with Triangular and Square Building Units and the Lowest Calculated Density for Porous Crystals

被引：299

作者：

Furukawa, Hiroyasu ^{[1
,2
]}

Go, Yong Bok ^{[1
,2
]}

Ko, Nakeun ^{[3
]}

Park, Young Kwan ^{[3
]}

Uribe-Romo, Fernando J. ^{[1
,2
]}

Kim, Jaheon ^{[3
]}

O'Keeffe, Michael ^{[1
,2
]}

Yaghi, Omar M. ^{[1
,2
,4
,5
]}

机构：

[1] Univ Calif Los Angeles, UCLA DOE Inst Genom & Prote, Ctr Global Mentoring, Ctr Reticular Chem, Los Angeles, CA 90095 USA

[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

[3] Soongsil Univ, Dept Chem, Seoul 156743, South Korea

[4] Korea Adv Inst Sci & Technol KAIST, NanoCentury KI, Taejon 305701, South Korea

[5] Korea Adv Inst Sci & Technol KAIST, Grad Sch EEWS WCU, Taejon 305701, South Korea

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 18期

关键词：

HIGH H-2 ADSORPTION; RETICULAR SYNTHESIS; HYDROGEN STORAGE; PORE-SIZE; NETS; COORDINATION; SURFACE; DESIGN; SITES; FUNCTIONALITY;

D O I：

10.1021/ic201376t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The concept and occurrence of isoreticular (same topology) series of metal organic frameworks (MOFs) is reviewed. We describe the preparation, characterization, and crystal structures of three new MOFs that are isoreticular expansions of known materials with the tbo (Cu-3(4,4',4 ''-(benzene-1,3,5-triyl-tris(benzene-4,1-diy1))tribenzoate)(2), MO F-399) and pto topologies (Cu-3(4,4',4 ''-(benzene-1,3,5-triyltribenzoate)(2), MOF-143; Cu-3(4,4',4 ''-(triazine-2,4,6-triyl-tris-(benzene-4,1-diyl))tribenzoate)(2), MOF-388). One of these materials (MOF-399) has a unit cell volume 17 times larger than that of the first reported material isoreticular to it, and has the highest porosity (94%) and lowest density (0.126 g cm(-3)) of any MOFs reported to date.

引用

页码：9147 / 9152

页数：6

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