First total synthesis of (+)-hyacinthacine A2

被引：73

作者：

Rambaud, L ^{[1
]}

Compain, P ^{[1
]}

Martin, OR ^{[1
]}

机构：

[1] Univ Orleans, CNRS, Inst Chim Organ & Analyt, F-45067 Orleans, France

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 13期

关键词：

D O I：

10.1016/S0957-4166(01)00324-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first synthesis of (+)-hyacinthacine A(2) has been achieved in six steps from 2,3,5-tri-O-benZyl-D-arabinofuranose in an overall yield of 11%. The structure of this natural product was thus unambiguously established as (1R,2R,3R,7aR)-1,2-dihydroxy-3-1-lydroxymethylpyrrolizidine. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1807 / 1809

页数：3

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