Enabling Sodium Batteries Using Lithium-Substituted Sodium Layered Transition Metal Oxide Cathodes

被引：411

作者：

Kim, Donghan ^{[2
]}

Kang, Sun-Ho ^{[2
]}

Slater, Michael ^{[2
]}

Rood, Shawn ^{[2
]}

Vaughey, John T. ^{[2
]}

Karan, Naba ^{[1
]}

Balasubramanian, Mahalingam ^{[1
]}

Johnson, Christopher S. ^{[2
]}

机构：

[1] Argonne Natl Lab, Adv Photon Source, Xray Sci Div, Argonne, IL 60439 USA

[2] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA

来源：

ADVANCED ENERGY MATERIALS | 2011年 / 1卷 / 03期

基金：

美国能源部; 加拿大自然科学与工程研究理事会;

关键词：

ELECTRODES; LI; NA; MN;

D O I：

10.1002/aenm.201000061

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Layered Na 0.85Li 0.17Ni 0.21Mn 0.64O 2 is synthesized and evaluated as a cathode in Na batteries. The resulting P2 crystal structure allows for single-phase reversible Na intercalation reaction demonstrating 100 mAhg -1. The cathode can be discharged with high rate (65 mAhg -1 at 25 C rate). The presence of Li and the electronic ordering of Ni(II)/Mn(IV) in the transition metal layer is responsible for material stability. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：333 / 336

页数：4

共 20 条

[1] Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteries [J].

Armstrong, AR ;

Bruce, PG .

NATURE, 1996, 381 (6582) :499-500

[2] A comparative investigation of the Li insertion properties of the novel fluorophosphate phases, NaVPO4FandLiVPO4F [J].

Barker, J ;

Saidi, MY ;

Swoyer, JL .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (10) :A1670-A1677

[3] A sodium-ion cell based on the fluorophosphate compound NaVPO4F [J].

Barker, J ;

Saidi, MY ;

Swoyer, JL .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (01) :A1-A4

[4] Ion-exchange properties of P2-NaxMnO2:: evidence of the retention of the layer structure based on chemical reactivity data and electrochemical measurements of lithium cells [J].

Caballero, A ;

Hernán, L ;

Morales, J ;

Sánchez, L ;

Santos, J .

JOURNAL OF SOLID STATE CHEMISTRY, 2003, 174 (02) :365-371

[5] Synthesis and characterization of high-temperature hexagonal P2-Na0.6MnO2 and its electrochemical behaviour as cathode in sodium cells [J].

Caballero, A ;

Hernán, L ;

Morales, J ;

Sánchez, L ;

Peña, JS ;

Aranda, MAG .

JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (04) :1142-1147

[6] ORTHORHOMBIC NAXMNO2 AS A CATHODE MATERIAL FOR SECONDARY SODIUM AND LITHIUM POLYMER BATTERIES [J].

DOEFF, MM ;

PENG, MY ;

MA, YP ;

DEJONGHE, LC .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (11) :L145-L147

[7] Crystal Structure and Electrochemical Properties of A2MPO4F Fluorophosphates (A = Na, Li; M = Fe, Mn, Co, Ni) [J].

Ellis, Brian L. ;

Makahnouk, W. R. Michael ;

Rowan-Weetaluktuk, W. N. ;

Ryan, D. H. ;

Nazar, Linda F. .

CHEMISTRY OF MATERIALS, 2010, 22 (03) :1059-1070

[8] Electrodes with high power and high capacity for rechargeable lithium batteries [J].

Kang, KS ;

Meng, YS ;

Bréger, J ;

Grey, CP ;

Ceder, G .

SCIENCE, 2006, 311 (5763) :977-980

[9]

KIMS D, 2010, ELECTROCHEM COMMUN, V12, P1618

[10] Electrochemical intercalation activity of layered NaCrO2 vs. LiCrO2 [J].

Komaba, Shinichi ;

Takei, Chikara ;

Nakayama, Tetsuri ;

Ogata, Atsushi ;

Yabuuchi, Naoaki .

ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (03) :355-358

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