Mechanism-based design of a ROMP catalyst for sequence-selective copolymerization

被引：76

作者：

Bornand, M ^{[1
]}

Chen, P ^{[1
]}

机构：

[1] ETH, Organ Chem Lab, CH-8092 Zurich, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 48期

关键词：

alkenes; copolymerization; homogeneous catalysis; metathesis; ruthenium;

D O I：

10.1002/anie.200502606

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Back and forth like a metronome is how the carbene moiety swings in a dual-site catalyst which produces a predominantly alternating copolymer of norbornene and cyclooctene from a one-pot reaction of appropriate mixtures of the two monomers (see scheme). The alternating sequence of the polymer was confirmed by NMR spectroscopy and gel-permeation gravimetric analysis. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：7909 / 7911

页数：3

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