Enantioselective rhodium catalyzed hydroboration of olefins using chiral bis(aminophosphine) ligands

被引：18

作者：

Brunel, JM ^{[1
]}

Buono, G ^{[1
]}

机构：

[1] Fac St Jerome, ENSPICAM, CNRS, UMR 6516, F-13397 Marseille 20, France

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 18期

关键词：

D O I：

10.1016/S0040-4039(99)00538-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of new chiral bis(aminophosphine) ligands 1-5 was achieved and assessed in the enantioselective rhodium catalyzed hydroboration of various olefins with catecholborane. Enantioselectivities up to 77% were obtained. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：3561 / 3564

页数：4

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