Reaction of tetramethylammonium fluoride with trifluoromethyltrimethylsilane

被引：24

作者：

Adams, DJ ^{[1
]}

Clark, JH ^{[1
]}

Hansen, LB ^{[1
]}

Sanders, VC ^{[1
]}

Tavener, SJ ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1998年 / 92卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

Ruppert's reagent; trifluoromethane; TMAF; fluorodenitration;

D O I：

10.1016/S0022-1139(98)00273-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetramethylammonium fluoride reacts with either triluoromethyltrimethylsilane or trimethylsilylacetonitrile in acetonitrile to form a pentacoordinate silicon species, which can act as a source of either fluoride or cyanomethyl carbanion, depending on substrate. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：123 / 125

页数：3

共 8 条

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