Sodium cobalt aminomethylidenediphosphonate with a novel open framework structure

被引：27

作者：

Bao, SS

Zheng, KM ^{[1
]}

Liu, YJ

Xu, W

Feng, SH

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Jilin Univ, State Key Lab Inorgan Syntheses & Preparat Chem, Changchun 130023, Peoples R China

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 17期

关键词：

D O I：

10.1021/ic0344158

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This paper reports the synthesis and crystal structure of a cobalt aminomethylenediphosphonate compound NaCo2{NH3CH(PO3)(PO3H0.5)}(2)(H2O)(2).xH(2)O (1). It shows a novel open framework structure in which layers of Co-2{NH3CH(PO3)(PO3H0.5)}(2)(H2O)(2) are connected by NaO6 linkages. The magnetic studies show a dominant antiferromagnetic exchange between the Co(II) ions.

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页码：5037 / 5039

页数：3

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