Further evidences about the role of bis(thiazolin-2-ylidene)s as the actual catalytic species in the generalised benzoin condensation.

被引:5
作者
LopezCalahorra, F
Castro, E
Ochoa, A
Marti, J
机构
[1] Dept. de Química Organica, Universitat of Barcelona, E-08028 Barcelona, Marti i Franquès
关键词
D O I
10.1016/0040-4039(96)01023-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Applying our mechanistic hypothesis about the real catalytic species in the benzoin condensation catalysed by thiazolium salts plus bases, we have succeed in the extension to aldehydes different from formaldehyde of a previously described method of synthesis of alpha-aminoketones combining Mannich reaction and benzoin condensation. Copyright (C) 1996 Published by Elsevier Science Ltd
引用
收藏
页码:5019 / 5022
页数:4
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