Aqueous-phase room-temperature synthesis of gold nanoribbons: Soft template effect of a gemini surfactant

被引:83
作者
Bakshi, Mandeep Singh [1 ,3 ]
Possmayer, Fred [2 ]
Petersen, Nils O. [1 ,4 ]
机构
[1] Univ Western Ontario, Dept Chem, London, ON N6A 5A5, Canada
[2] Univ Western Ontario, Dept Biochem, London, ON N6A 5A5, Canada
[3] Guru Nanak Dev Univ, Dept Chem, Amritsar 143005, Punjab, India
[4] Natl Inst Nanotechnol, Edmonton, AB, Canada
关键词
D O I
10.1021/jp801306x
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Gold (Au) nanoribbons were synthesized in aqueous phase under ambient conditions by using dimethylene bis(tetradecyldimethyl-ammonium bromide) (14-2-14) as a capping agent as well as a soft template. A two steps seed-growth (S-G) method was used. The first step of S-G method mainly gave nanorods of high aspect ratio along with nanoparticles of other shapes, but the next step produced mainly fine An nanoribbons of several micrometers long, 50-150 nm wide, and approximate to 5 nm thick. They were characterized by transmission electron microscopy, X-ray photoelectron spectroscopy, energy dispersive X-ray, and X-ray diffraction analysis. Isotropic liquid crystalline phase of 14-2-14 provided a soft template effect and derived nanorods of high aspect ratios toward nanoribbon formation at room temperature.
引用
收藏
页码:8259 / 8265
页数:7
相关论文
共 61 条
[1]   ALKANEDIYL-ALPHA,OMEGA-BIS(DIMETHYLALKYLAMMONIUM BROMIDE) SURFACTANTS .2. STRUCTURE OF THE LYOTROPIC MESOPHASES IN THE PRESENCE OF WATER [J].
ALAMI, E ;
LEVY, H ;
ZANA, R ;
SKOULIOS, A .
LANGMUIR, 1993, 9 (04) :940-944
[2]   Thermodynamics of molecular self-assembly of cationic gemini and related double chain surfactants in aqueous solution [J].
Bai, GY ;
Wang, JB ;
Yan, HK ;
Li, ZX ;
Thomas, RK .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (15) :3105-3108
[3]   Polymer-controlled synthesis of silver nanobelts and hierarchical nanocolumns [J].
Bai, Jingwei ;
Qin, Yao ;
Jiang, Chengyang ;
Qi, Limin .
CHEMISTRY OF MATERIALS, 2007, 19 (14) :3367-+
[4]   Au and Au-Ag bimetallic nanoparticles synthesized by using 12-3-12 cationic Gemini surfactant as template [J].
Bakshi, Mandeep Singh ;
Sharma, Poonam ;
Banipal, Tarlok Singh .
MATERIALS LETTERS, 2007, 61 (28) :5004-5009
[5]   Role of different phospholipids in the synthesis of pearl-necklace-type gold-silver bimetallic nanoparticles as bioconjugate materials [J].
Bakshi, Mandeep Singh ;
Possmayer, Fred ;
Petersen, Nils O. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (38) :14113-14124
[6]   Lamellar phase supported synthesis of colloidal gold nanoparticles, nanoclusters, and nanowires [J].
Bakshi, Mandeep Singh ;
Sharma, Poonam ;
Banipal, Tarlok Singh ;
Kaur, Gurinder ;
Torigoe, Kanjiro ;
Petersen, Nils O. ;
Possmayer, Fred .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2007, 7 (03) :916-924
[7]   Simultaneous synthesis of au and cu nanoparticles in pseudo-core-shell type arrangement facilitated by DMPG and 12-6-12 capping agents [J].
Bakshi, Mandeep Singh ;
Possmayer, Fred ;
Petersen, Nils O. .
CHEMISTRY OF MATERIALS, 2007, 19 (06) :1257-1266
[8]   Photophysical evaluation of synergism from critical micelle temperature of mixed triblock polymer micelles [J].
Bakshi, Mandeep Singh ;
Kaur, Navjot ;
Mahajan, Rakesh Kumar .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2007, 186 (2-3) :349-356
[9]   Spectroscopic investigation on the hydrophobicity in the mixtures of nonionic plus twin tail alkylammonium bromide surfactants [J].
Bakshi, MS ;
Singh, K ;
Kaur, G ;
Yoshimura, T ;
Esumi, K .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2006, 278 (1-3) :129-139
[10]   Mixed micelles of monomeric and dimeric cationic surfactants with phospholipids: effect of hydrophobic interactions [J].
Bakshi, MS ;
Singh, J ;
Kaur, G .
CHEMISTRY AND PHYSICS OF LIPIDS, 2005, 138 (1-2) :81-92