Origin of delayed fluorescence of a ladder-type methyl-poly(para-phenylene) doped with Pt(II)octaethylporphyrin

被引：21

作者：

Bagnich, SA

Bässler, H

机构：

[1] Byelarussian Acad Sci, Inst Atom & Mol Phys, Minsk 220072, BELARUS

[2] Univ Marburg, Instr Phys Kern & Makromol Chem, D-35032 Marburg, Germany

[3] Univ Marburg, Wissensch Zentrum Mat Wissensch, D-35032 Marburg, Germany

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 381卷 / 3-4期

关键词：

D O I：

10.1016/j.cplett.2003.09.140

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Luminescence of a ladder-type methyl-poly(para-phenylene) (MeLPPP) doped with 5% (by weight) platinum-porphyrin (PtOEP) has been investigated. It is shown that upon exciting in the spectral range of absorption of the guest the delayed fluorescence of the polymer is observed. Based upon field quenching of delayed fluorescence it is argued that it originates from an exciplex between PtOEP and MeLPPP generated by exciting the S-1 state of PtOEP. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：464 / 470

页数：7

共 23 条

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