Synthesis and dehydrative condensation of monomeric hydroxoruthenium complexes with hydrotris(3,5-diisopropylpyrazolyl)borate ligand, TpiPr2Ru(L2)-OH (L2 = dppe, bipy)

被引：18

作者：

Akita, M ^{[1
]}

Takahashi, Y ^{[1
]}

Hikichi, S ^{[1
]}

Moro-oka, Y ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 01期

关键词：

D O I：

10.1021/ic000520v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Monomeric neutral hydroxoruthenium complexes, Tp(2)(iPr)RuOH(L-2) (L-2 = dppe, bipy), are prepared by deprotonation of aquo complexes, and it is confirmed that dehydrative condensation reaction of the hydroxo complexes with carboxylic acids involves protonation of hydroxo ligand followed by replacement of the resultant aquo ligand by the nucleophile.

引用

页码：169 / +

页数：5

共 23 条

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