Modes of operation and pH control as enhancement factors for partial nitrification with oxygen transport limitation

被引:82
作者
Ciudad, G. [1 ]
Gonzalez, R. [1 ]
Bornhardt, C. [1 ]
Antileo, C. [1 ]
机构
[1] Univ La Frontera, Dept Chem Engn, Temuco, Chile
关键词
SBR; rotating disk biofilm reactor; partial nitrification; pH control; oxygen limitation;
D O I
10.1016/j.watres.2007.06.036
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Sequencing batch (SBR) and continuous operation modes were applied using different pH control strategies to enhance partial nitrification in a biofilm rotating disk reactor. The pH control strategies were supervisory control in the range of 7.5-8.6 and fixed pH at 7.5 and 8.5, at dissolved oxygen (DO) concentrations in the range of 0.6-5.0 mg O-2/L. Supervisory pH control enabled operation at a free ammonia concentration inhibitory to the nitrite-oxidizing bacteria (NOB) and an optimum for the ammonia-oxidizing bacteria (AOB). The results indicate that both operation modes were simultaneously controlled by oxygen transport and micro-kinetics (influenced by pH and NH3). The SBR mode with supervisory pH control presented more stable partial nitrification-nitrite accumulation > 80% for 249 days than continuous operation. Molecular analyses showed that the SBR operation with supervisory pH control at low DO concentrations contributed to the enrichment of the AOB (> 95%) over the NOB (< 5%) populations. Therefore, it can be stated that a suitable pH control strategy can act as an enhancement factor of partial nitrification even under oxygen-transport-limiting conditions. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4621 / 4629
页数:9
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