Bio-lnspired Borate Cross-Linking in Ultra-Stiff Graphene Oxide Thin Films

被引：308

作者：

An, Zhi ^{[2
]}

Compton, Owen C. ^{[2
]}

Putz, Karl W. ^{[1
]}

Brinson, L. Catherine ^{[1
]}

Nguyen, SonBinh T. ^{[2
]}

机构：

[1] Northwestern Univ, Dept Mech Engn & Mat Sci & Engn, Evanston, IL 60208 USA

[2] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

ADVANCED MATERIALS | 2011年 / 23卷 / 33期

关键词：

CELL-WALL; MECHANICAL-PROPERTIES; RHAMNOGALACTURONAN-II; GRAPHITE OXIDE; POLYMER NANOCOMPOSITES; PLANT-CELL; BORON; PAPER; POLYVINYL-ALCOHOL); POLYSACCHARIDE;

D O I：

10.1002/adma.201101544

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Adjacent graphene oxide nanosheets in a thin-film structure have been covalently cross-linked in a fashion similar to the cell walls of higher-order plants. The resulting ultrastiff structure exhibits a maximum storage modulus of 127 GPa that can be tuned by varying borate concentration.

引用

页码：3842 / +

页数：6

共 32 条

[1] Multi-objective optimization in material design and selection [J].

Ashby, MF .

ACTA MATERIALIA, 2000, 48 (01) :359-369

[2] A CRITICAL-EVALUATION OF THE THERMODYNAMIC DATA FOR BORON IONS, ION-PAIRS, COMPLEXES, AND POLYANIONS IN AQUEOUS-SOLUTION AT 298.15-K AND 1-BAR [J].

BASSETT, RL .

GEOCHIMICA ET COSMOCHIMICA ACTA, 1980, 44 (08) :1151-1160

[3] Boron in plant structure and function [J].

Blevins, DG ;

Lukaszewski, KM .

ANNUAL REVIEW OF PLANT PHYSIOLOGY AND PLANT MOLECULAR BIOLOGY, 1998, 49 :481-500

[4] Why boron? [J].

Bolaños, L ;

Lukaszewski, K ;

Bonilla, I ;

Blevins, D .

PLANT PHYSIOLOGY AND BIOCHEMISTRY, 2004, 42 (11) :907-912

[5] MECHANICAL-PROPERTIES OF BORATE CROSSLINKED POLYVINYL-ALCOHOL) GELS [J].

CHENG, ATY ;

RODRIGUEZ, F .

JOURNAL OF APPLIED POLYMER SCIENCE, 1981, 26 (11) :3895-3908

[6] Graphene Oxide, Highly Reduced Graphene Oxide, and Graphene: Versatile Building Blocks for Carbon-Based Materials [J].

Compton, Owen C. ;

Nguyen, SonBinh T. .

SMALL, 2010, 6 (06) :711-723

[7] Preparation and characterization of graphene oxide paper [J].

Dikin, Dmitriy A. ;

Stankovich, Sasha ;

Zimney, Eric J. ;

Piner, Richard D. ;

Dommett, Geoffrey H. B. ;

Evmenenko, Guennadi ;

Nguyen, SonBinh T. ;

Ruoff, Rodney S. .

NATURE, 2007, 448 (7152) :457-460

[8] C-13 MAGNETIC-RESONANCE SPECTROSCOPIC EVIDENCE FOR FORMATION OF BORATE COMPLEXES OF POLYHYDROXY COMPOUNDS [J].

GORIN, PAJ ;

MAZUREK, M .

CARBOHYDRATE RESEARCH, 1973, 27 (02) :325-339

[9] LOCALIZATION OF BORON IN CELL-WALLS OF SQUASH AND TOBACCO AND ITS ASSOCIATION WITH PECTIN - EVIDENCE FOR A STRUCTURAL ROLE OF BORON IN THE CELL-WALL [J].

HU, HI ;

BROWN, PH .

PLANT PHYSIOLOGY, 1994, 105 (02) :681-689

[10] Species variability in boron requirement is correlated with cell wall pectin [J].

Hu, HN ;

Brown, PH ;

Labavitch, JM .

JOURNAL OF EXPERIMENTAL BOTANY, 1996, 47 (295) :227-232

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