Preparation of a novel diphosphine-palladium macrocyclic complex possessing a molecular recognition site. Oxidative addition studies

被引:14
作者
Larsen, J
Rasmussen, BS
Hazell, RG
Skrydstrup, T
机构
[1] Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark
[2] Aarhus Univ, Interdisciplinary Nanosci Ctr, DK-8000 Aarhus C, Denmark
关键词
D O I
10.1039/b309863j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A disphosphine-palladium(0) complex capable of recognising barbiturates has been prepared. Oxidative addition studies with a barbitiurate:aryl iodide conjugate provided new Pd(II) complexes where the positioning of the Pd-bound aryl group is controlled by the molecular recognition event.
引用
收藏
页码:202 / 203
页数:2
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