In situ XRD studies of the hydration degree of the polymeric membrane in a fuel cell

被引:17
作者
Albertini, VR [1 ]
Paci, B
Generosi, A
Panero, S
Navarra, MA
di Michiel, M
机构
[1] ISM CNR, I-00133 Rome, Italy
[2] Univ Roma La Sapienza, Dipartimento Chim, Rome, Italy
[3] European Synchrotron Radiat Facil, F-38043 Grenoble, France
关键词
D O I
10.1149/1.1817888
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
One factor influencing the performances of polymer electrolyte membrane fuel cells (PEMFCs) is the degree of hydration of their membranes. Until now, only theoretical calculations of the number of water molecules contained in the membranes, few studies of the distribution of water in working fuel cell membranes and ex situ measurements, have been carried out. In the present study, we report the first experimental determination of a dehydration process occurring in the polymeric membrane of a fuel cell, observed in real time by in situ X-ray diffraction (XRD) of a very high-energy synchrotron radiation. (C) 2004 The Electrochemical Society.
引用
收藏
页码:A519 / A521
页数:3
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