Recent developments in chemiluminescence and photochemical reaction detection for capillary electrophoresis

被引:45
作者
Kuyper, C [1 ]
Milofsky, R [1 ]
机构
[1] Ft Lewis Coll, Dept Chem, Durango, CO 81301 USA
关键词
chemiluminescence; photochemical reaction detection; capillary electrophoresis;
D O I
10.1016/S0165-9936(01)00066-8
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The remarkable resolution and ability to analyze small samples make capillary electrophoresis (CE) an attractive technique. However, analysis in capillary dimensions makes detection a formidable challenge. Over the past decade there has been increased interest in coupling chemiluminescence (CL) detection and photochemical reaction detection (PCRD) with CE. Much of this appeal stems from the proven sensitivity and selectivity of CL detection and PCRD coupled to HPLC. The current state of CL and PCRD and the limitations of CE-CL and CE-PCRD are discussed. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:232 / 240
页数:9
相关论文
共 32 条
[1]   PHOTOCHEMICAL-REACTION COUPLED TO SOLID-STATE PEROXYOXALATE CHEMILUMINESCENCE FOR THE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHIC DETECTION OF COMPOUNDS HAVING WEAK CHROMOPHORES [J].
AICHINGER, I ;
GUBITZ, G ;
BIRKS, JW .
JOURNAL OF CHROMATOGRAPHY, 1990, 523 :163-172
[2]  
Beale SC, 1998, ANAL CHEM, V70, p279R
[3]  
Birks J.W., 1982, TRAC TRENDS ANAL CHE, V1, P361
[4]  
BIRKS JW, 1989, CHEMILUMINESCENCE PH
[5]   Chemiluminescence detection in capillary electrophoresis [J].
Campana, AMG ;
Baeyens, WRG ;
Zhao, YN .
ANALYTICAL CHEMISTRY, 1997, 69 (03) :A83-A88
[6]   END-COLUMN CHEMILUMINESCENCE DETECTOR FOR CAPILLARY ELECTROPHORESIS [J].
DADOO, R ;
SETO, AG ;
COLON, LA ;
ZARE, RN .
ANALYTICAL CHEMISTRY, 1994, 66 (02) :303-306
[7]  
Dadoo R., 1992, J HIGH RES CHROMATOG, V15, P133
[8]   Coupling photochemical reaction detection based on singlet oxygen sensitization to capillary electrochromatography [J].
Dickson, J ;
Odom, M ;
Ducheneaux, F ;
Murray, J ;
Milofsky, RE .
ANALYTICAL CHEMISTRY, 2000, 72 (14) :3038-3042
[9]  
DICKSON JA, 1997, J HIGH RES CHROMATOG, V20, P643
[10]   On-line electrogenerated Ru(bpy)(3)(3+) chemiluminescent detection of beta-blockers separated with capillary electrophoresis [J].
Forbes, GA ;
Nieman, TA ;
Sweedler, JV .
ANALYTICA CHIMICA ACTA, 1997, 347 (03) :289-293