Oligomeric phenylenevinylene with cross dipole arrangement and amorphous morphology: Enhanced solid-state luminescence efficiency and electroluminescence performance

被引:75
作者
He, F
Xu, H
Yang, B
Duan, Y
Tian, LL
Huang, KK
Ma, YG [1 ]
Liu, SY
Feng, SH
Shen, JC
机构
[1] Jilin Univ, Minist Educ, Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China
[2] Jilin Univ, Natl Lab Integrated Optoelect, Changchun 130012, Peoples R China
[3] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
关键词
D O I
10.1002/adma.200501239
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new oligo(phenylenevinylene) linking three distyrylbenzene (DSB) molecules through a central terphenyl group is reported (see Figure). The resultant DSB trimer with an amorphous structure in the solid state exhibits excellent thermal stability and intense blue photoluminescence. The maximum luminance approaching 4000 cd m(-2) and efficiency up to 3.5 cd A(-1) can be obtained in the corresponding light-emitting devices with a low turn-on voltage (similar to 4 V).
引用
收藏
页码:2710 / +
页数:6
相关论文
共 27 条
[1]   DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE [J].
BECKE, AD .
JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5648-5652
[2]   Bright white small molecular organic light-emitting devices based on a red-emitting guest-host layer and blue-emitting 4,4′-bis(2,2′-diphenylvinyl)-1,1′-biphenyl [J].
Cheon, KO ;
Shinar, J .
APPLIED PHYSICS LETTERS, 2002, 81 (09) :1738-1740
[3]  
Cornil J, 2001, ADV MATER, V13, P1053, DOI 10.1002/1521-4095(200107)13:14<1053::AID-ADMA1053>3.0.CO
[4]  
2-7
[5]   Influence of interchain interactions on the absorption and luminescence of conjugated oligomers and polymers:: A quantum-chemical characterization [J].
Cornil, J ;
dos Santos, DA ;
Crispin, X ;
Silbey, R ;
Brédas, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (06) :1289-1299
[6]   1,3,6,8-tetraphenylpyrene derivatives:: Towards fluorescent liquid-crystalline columns? [J].
de Halleux, V ;
Calbert, JP ;
Brocorens, P ;
Cornil, J ;
Declercq, JP ;
Brédas, JL ;
Geerts, Y .
ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (07) :649-659
[7]   High brightness and efficiency blue light-emitting polymer diodes [J].
Grice, AW ;
Bradley, DDC ;
Bernius, MT ;
Inbasekaran, M ;
Wu, WW ;
Woo, EP .
APPLIED PHYSICS LETTERS, 1998, 73 (05) :629-631
[8]   Calix[4]oligophenylenevinylene:: a new rigid core for the design of π-conjugated liquid crystalline derivatives [J].
Gu, T ;
Accorsi, G ;
Armaroli, N ;
Guillon, D ;
Nierengarten, JF .
TETRAHEDRON LETTERS, 2001, 42 (12) :2309-2312
[9]   Synthesis, characteristics and luminescence properties of oligo(phenylenevinylene) dimers with a biphenyl linkage center [J].
He, F ;
Cheng, G ;
Zhang, HQ ;
Zheng, Y ;
Xie, ZQ ;
Yang, B ;
Ma, YG ;
Liu, SY ;
Shen, JC .
CHEMICAL COMMUNICATIONS, 2003, (17) :2206-2207
[10]   Stereocontrolled synthesis and optical properties of all-cis poly(phenylene vinylenes) (PPVs): a method for direct patterning of PPVs [J].
Katayama, H ;
Nagao, M ;
Nishimura, T ;
Matsui, Y ;
Umeda, K ;
Akamatsu, K ;
Tsuruoka, T ;
Nawafune, H ;
Ozawa, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (12) :4350-4353