Adsorption isotherms of benzene and toluene on corn grain-based carbon monolith at (303.15, 313.15, and 323.15) K

被引:19
作者
Balathanigaimani, M. S. [1 ,2 ]
Shim, Wang-Geun [1 ,2 ]
Lee, Min-Joo [1 ,2 ]
Lee, Jae-Wook [3 ]
Moon, Hee [1 ,2 ]
机构
[1] Chonnam Natl Univ, Ctr Funct Nano Fine Chem, Kwangju 500757, South Korea
[2] Chonnam Natl Univ, Fac Appl Chem Engn, Kwangju 500757, South Korea
[3] Chosun Univ, Dept Chem & Biochem Engn, Kwangju 501759, South Korea
关键词
D O I
10.1021/je700575g
中图分类号
O414.1 [热力学];
学科分类号
摘要
The adsorption isotherms of benzene and toluene on a newly made corn grain-based carbon monolith were measured at (303.15, 315.15, and 323.15) K using a gravimetric method. The Toth isotherm model was adopted to fit the adsorption equilibrium data of benzene and toluene. The Dubinin-Astakhov equation was used to calculate the total micropore volume of carbon monolith. By using the Clausius-Clapeyron equation, the surface energetic character of the carbon monolith was analyzed. The thermal desorption works were carried out to investigate the interaction between the adsorbates and monolith.
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页码:732 / 736
页数:5
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