The use of a portable total reflection X-ray fluorescence spectrometer for field investigation

被引:25
作者
Mages, M
Woelfl, S
Ovári, M
von Tümpling, W
机构
[1] UFZ Helmholtz Ctr Environm Res, Ctr Environm Res Leipzig Halle, Dept Inland Water Res Magdeburg, D-39114 Magdeburg, Germany
[2] Univ Austral Chile, Inst Zool, Valdivia, Chile
关键词
total reflection X-ray fluorescence; portable TXRF; field experiments; contamination; elbe river; Chilean lakes; surface water;
D O I
10.1016/S0584-8547(03)00197-6
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
A newly developed, portable total reflection X-ray fluorescence (TXRF) spectrometer was tested during a field campaign on Chilean lakes and a German river in January 2002. The field measurements were compared with laboratory measurements carried out on a stationary instrument in the German laboratory. For method validation certified reference material (NIST SRM 1640 Trace elements in natural water) and water samples from different freshwater sources were analyzed with both techniques and evaluated statistically. Based on these preliminary results, it could be concluded that the portable TXRF is a useful technique for the quantitative elemental screening of freshwater samples during field campaigns. Future tests with biological samples (e.g. biofilms and zooplankton), and suspended matter will provide information about the suitability of the portable TXRF for these materials. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:2129 / 2138
页数:10
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