The growth and dissolution of sodium chloride in a fluidized bed crystallizer

被引:44
作者
Al-Jibbouri, S [1 ]
Ulrich, J [1 ]
机构
[1] Univ Halle Wittenberg, Bachbereich Ingenieurwissensch, Inst Verfahrenstech Therm Verfahrenstech, D-06099 Halle Saale, Saale, Germany
关键词
diffusion step; impurity; effectiveness factor; growth rate; integration step;
D O I
10.1016/S0022-0248(01)01656-6
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The growth and dissolution rates of NaCl crystals were investigated in a fluidized bed crystallizer. In the experiments the supersaturation and impurity concentration in the solution were varied. The growth rate was interpreted in terms of supersaturation levels. The orders and rate constants were reported. The effectiveness factors were estimated from the growth rate data to evaluate the relative magnitude of the two resistances in series, diffusion and integration. The effectiveness factor results indicate that the controlling mechanism is contributing by means of the diffusion and the integration steps on the crystal growth of NaCl from pure solution. However, the presence of impurities lead to a more important role of the integration step. (C) 2002 Elsevier Science BN. All rights reserved.
引用
收藏
页码:237 / 246
页数:10
相关论文
共 13 条
[1]  
ALJIBBOURI S, 2001, P INT C PART TECHN N
[2]  
ALSABBAGH A, 1996, THESIS RWTH AACHEN A
[3]  
FABIAN J, 1996, THESIS U BREMEN BREM
[4]   CONCEPT OF EFFECTIVENESS FACTORS IN CRYSTAL GROWTH [J].
GARSIDE, J .
CHEMICAL ENGINEERING SCIENCE, 1971, 26 (09) :1425-&
[5]  
Hayakawa T., 1973, Heat Transfer - Japanese Research, V2, P104
[6]  
KRUSE M, 1993, THSIS U BREMEN BREME
[7]  
LANGER H, 1985, THESIS RWTH AACHEN A
[8]   NONISOTHERMAL EFFECTIVENESS FACTORS AND THE ROLE OF HEAT-TRANSFER IN CRYSTAL-GROWTH FROM SOLUTIONS AND MELTS [J].
MATSUOKA, M ;
GARSIDE, J .
CHEMICAL ENGINEERING SCIENCE, 1991, 46 (01) :183-192
[9]   GROWTH AND DISSOLUTION OF POTASSIUM SULPHATE CRYSTALS IN A FLUIDIZED BED CRYSTALLIZER [J].
MULLIN, JW ;
GASKA, C .
CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1969, 47 (05) :483-&
[10]  
Mullin JW., 1993, CRYSTALLIZATION