Photochemistry of bicyclo[2.2.2]octenones: an uncommon oxidative decarbonylation

被引:20
作者
Lee, TH [1 ]
Rao, PD [1 ]
Liao, CC [1 ]
机构
[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30043, Taiwan
关键词
D O I
10.1039/a901182j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Several substituted 3,3-dialkoxy-5-methoxycarbonyIbicyclo[2.2.2]oct-5-en-2-ones underwent unusual oxidative decarbonylation to produce polysubstituted cyclohexenes upon direct irradiation and usual ODPM rearrangement under sensitized conditions. A plausible mechanism for the oxidative decarbonylation is also given.
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页码:801 / 802
页数:2
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