Transfer of alk-1-enyl group from boron to boron:: preparation of B-[(E)-alk-1-enyl]-9-borabicyclo[3.3.1]nonane

被引：12

作者：

Hoshi, M ^{[1
]}

Shirakawa, K ^{[1
]}

Arase, A ^{[1
]}

机构：

[1] Kitami Inst Technol, Dept Appl & Environm Chem, Kitami, Hokkaido 0908507, Japan

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 11期

关键词：

D O I：

10.1039/a801939h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of (E)-alk-1-enyldicyclohexylborane 1 with B-methoxy-9-borabicyclo[3.3.1]nonane (B-MeO-9-BBN) at 0 degrees C results in transfer of alk-1-enyl group from boron to boron to give B-[(E)-alk-1-enyl]-9-BBN 2 with retention of configuration.

引用

页码：1225 / 1226

页数：2

共 9 条

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