Triple-decker trinuclear porphinatoruthenium(II) complexes bridged with pyrazine or 4,4'-bipyridine-preparation and electrochemical oxidation

被引：11

作者：

Endo, A

Tagami, U

Wada, Y

Saito, M

Shimizu, K

Sato, GP

机构：

来源：

CHEMISTRY LETTERS | 1996年 / 03期

关键词：

D O I：

10.1246/cl.1996.243

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two triple-decker trinuclear porphinatoruthenium(II) complexes bridged with pyrazine (pyr) or 4,4'-bipyridine (4,4'-bpy), [{(CO)(oep)Ru-II}(mu-pyr){Ru-II(oep)}(mu-pyr){Ru-II(oep)(CO)}] (H(2)oep = octaethylporphine) and [{(CO)(tpp)Ru-II}(mu-4,4'-bpy){Ru-II(tpp)}(mu-4,4'-bpy){Ru-II(tpp)(CO)}] (H(2)tpp = tetraphenylporphine), have been prepared. The first trinuclear complex was electrochemically oxidized in four steps.

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页码：243 / 244

页数：2

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