Pinwheel motifs:: formation of unusual homo- and hetero-nuclear aggregates via bridging thiolates

被引：25

作者：

Amoroso, AJ ^{[1
]}

Chung, SSM ^{[1
]}

Spencer, DJE ^{[1
]}

Danks, JP ^{[1
]}

Glenny, MW ^{[1
]}

Blake, AJ ^{[1
]}

Cooke, PA ^{[1
]}

Wilson, C ^{[1
]}

Schröder, M ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 16期

关键词：

D O I：

10.1039/b303851c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The homohexanuclear complexes [Ni-2{Ni(L-1)}(4)](BF4)(4).MeCN, 1, [Pd-2{Pd(L-2)}(4)](BF4)(4), 2, and the heteropentanuclear aggregate [Cu-2{Ni(L-3)}(3)](PF6)(2), 3, all adopt a 'pin-wheel' type structural motif via thiolate bridging between square-planar Ni(II) or Pd(II) and between trigonal planar Cu(I) centres, respectively.

引用

页码：2020 / 2021

页数：2

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