Separation and photophysical properties of the ΔΔ, ΛΛ, ΔΛ, and ΛΔ stereoisomers of a dinuclear ruthenium(II) complex

被引：38

作者：

Browne, WR

O'Connor, CM

Villani, C

Vos, JG ^{[1
]}

机构：

[1] Dublin City Univ, Sch Chem Sci, Natl Ctr Sensor Res, Dublin 9, Ireland

[2] Univ G dAnnunzio, Dipartimento Sci Farmaco, I-66013 Chieti, Italy

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 21期

关键词：

D O I：

10.1021/ic010473m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The separation of the four stereoisomers of [(Ru(boy)2)2(bpt)](PF6)3 (where bpy=2,2′-bipyridine, Hbpt=3,5-bis(pyridin-2-yl)-1H-1,2,4-triazole) by semi-preparative HPLC is reported. The emission properties of the isomers obtained have been studied as a function of the enantiomeric purity of the solvent.

引用

页码：5461 / 5464

页数：4

共 37 条

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