Synthesis of 2-acyl-1,4-diketones via the diacylation of α,β-unsaturated ketones

被引：17

作者：

Li, NS

Yu, S

Kabalka, GW ^{[1
]}

机构：

[1] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

[2] Univ Tennessee, Dept Radiol, Knoxville, TN 37996 USA

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 17期

关键词：

D O I：

10.1021/om980303q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first example of a diacylation of the carbon-carbon double bond in alpha,beta-unsaturated ketones is described. The reaction of acylcyanocuprate reagents with alpha,beta-unsaturated ketones, followed by C-acylation, produces 2-acyl-1,4-diketones in good yields (50-89%).

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收藏

页码：3815 / 3818

页数：4

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