Vibrations of nitrous oxide:: Matrix isolation Fourier transform infrared spectroscopy of twelve N2O isotopomers

被引：53

作者：

Lapinski, A

Spanget-Larsen, J

Waluk, J

Radziszewski, JG ^{[1
]}

机构：

[1] Colorado Sch Mines, Dept Chem Engn, Golden, CO 80401 USA

[2] Natl Renewable Energy Lab, Golden, CO 80401 USA

[3] Roskilde Univ, Dept Chem & Life Sci, DK-4000 Roskilde, Denmark

[4] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland

来源：

JOURNAL OF CHEMICAL PHYSICS | 2001年 / 115卷 / 04期

关键词：

D O I：

10.1063/1.1383031

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Isotopically labeled nitrous oxide has been produced in solid nitrogen matrices using mixtures of nitrogen and water containing N-14, N-15, O-16, O-17, and O-18. All twelve possible N2O isotopomers have been obtained, and their fundamental, overtone and combination frequencies were assigned by the joint use of infrared spectroscopy and quantum chemical calculations (B3LYP/AUG-cc-pVTZ). Specific influence of the nitrogen matrix upon frequency and anharmonicity of the vibrations has been discussed. (C) 2001 American Institute of Physics.

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页码：1757 / 1764

页数：8

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共 140 条

[1] Theoretical investigation of the potential energy surfaces for the O(1D)+N2O reaction [J].

Akagi, H ;

Yokoyama, A ;

Fujimura, Y ;

Takayanagi, T .

CHEMICAL PHYSICS LETTERS, 2000, 324 (5-6) :423-429

[2] ON THE ABINITIO DETERMINATION OF HIGHER-ORDER FORCE-CONSTANTS AT NONSTATIONARY REFERENCE GEOMETRIES [J].

ALLEN, WD ;

CSASZAR, AG .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (04) :2983-3015

[3] A SYSTEMATIC STUDY OF MOLECULAR VIBRATIONAL ANHARMONICITY AND VIBRATION-ROTATION INTERACTION BY SELF-CONSISTENT-FIELD HIGHER-DERIVATIVE METHODS - LINEAR POLYATOMIC-MOLECULES [J].

ALLEN, WD ;

YAMAGUCHI, Y ;

CSASZAR, AG ;

CLABO, DA ;

REMINGTON, RB ;

SCHAEFER, HF .

CHEMICAL PHYSICS, 1990, 145 (03) :427-466

[4] VIBRATION-ROTATION BANDS OF N-14(2) O-16 - 1.2 MICRON-3.3 MICRON REGION [J].

AMIOT, C ;

GUELACHVILI, G .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1974, 51 (03) :475-491

[5] VIBRATION-ROTATION BANDS OF N-15(2)O-16-N-14(2)O-18 [J].

AMIOT, C .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1976, 59 (03) :380-395

[6] EXTENSION OF 106 SAMPLES FOURIER SPECTROMETRY TO INDIUM-ANTIMONIDE REGION - VIBRATION-ROTATION BANDS OF N-14(2)O-16 - 3.3-5.5 MU-M REGION [J].

AMIOT, C ;

GUELACHVILI, G .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1976, 59 (02) :171-190

[7] VIBRATION-ROTATION BANDS OF N-14N-15O-16-N-15N-14O-16 - 1.6-5.7 MU-M REGION [J].

AMIOT, C .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1976, 59 (02) :191-208

[8] Reactions of laser-ablated iron atoms with N2O, NO, and O-2 in condensing nitrogen. Infrared spectra and density functional calculations of ternary iron nitride oxide molecules [J].

Andrews, L ;

Chertihin, GV ;

Citra, A ;

Neurock, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (27) :11235-11241

[9] INFRARED-SPECTRA OF THE CO2=HF AND N2O=HF COMPLEXES IN SOLID ARGON AT 12-K [J].

ANDREWS, L ;

JOHNSON, GL .

JOURNAL OF CHEMICAL PHYSICS, 1982, 76 (06) :2875-2880

[10] New information on the ozone monomer photochemistry at 266 nm in nitrogen matrix [J].

Bahou, M ;

Schriver-Mazzuoli, L ;

Camy-Peyret, C ;

Schriver, A .

JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (16) :6884-6891

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