Synthesis of pentafluorophenyl(meth)acrylate polymers:: New precursor polymers for the synthesis of multifunctional materials

被引：352

作者：

Eberhardt, M ^{[1
]}

Mruk, R ^{[1
]}

Zentel, R ^{[1
]}

Théato, P ^{[1
]}

机构：

[1] Johannes Gutenberg Univ Mainz, Inst Organ Chem, D-55099 Mainz, Germany

来源：

EUROPEAN POLYMER JOURNAL | 2005年 / 41卷 / 07期

关键词：

active ester monomers; multifunctional polymers; reactivity; polymer analogous reaction; poly(acrylamide); poly(pentafluorophenylacrylate);

D O I：

10.1016/j.eurpolymj.2005.01.025

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Pentafluorophenyl acrylate and -methacrylate were polymerized using AIBN as a thermal initiator. The obtained polymers were soluble polymeric active esters that could be used for the preparation of multifunctional polymers. The reactivity of poly(pentafluorophenylacrylate) and poly(pentafluorophenylmethacrylate) towards primary and secondary amines, as well as alcohols was investigated in a quantitative way. Both poly(active esters) reacted satisfactorily with aliphatic primary and secondary amines but only low conversion was found in the case of aromatic amines. Conversions of only 30% were reached when poly(pentafluorophenylacrylate) was treated with one equivalent of alcohol under base catalysis. In time resolved FT-IR studies the rate constants of the polymer analogous reactions were determined. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：1569 / 1575

页数：7

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