Design and synthesis of a sterically hindered pyridine and its encapsulation of silver(I) cation

被引：24

作者：

Bosch, E

Barnes, CL

机构：

[1] SW Missouri State Univ, Dept Chem, Springfield, MO 65804 USA

[2] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 13期

关键词：

D O I：

10.1021/ic001305h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The design and synthesis of a sterically hindered pyridine, 2,6-dimesitylpyridine, and its complexation of silver(I) salts is presented. X-ray crystal structural analysis of the light-stable bis(2,6-dimesityl)pyridine/silver(I) triflate complex clearly shows that the two pyridine ligands are mutually perpendicular, and the flanking mesityl groups thus effectively encapsulate the silver cation.

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页码：3234 / +

页数：4

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