Surface-initiated, enzymatic polymerization of biodegradable polyesters

被引：54

作者：

Yoon, KR

Lee, KB

Chi, YS

Yun, WS

Joo, SW

Choi, IS

机构：

[1] Korea Adv Inst Sci & Technol, Ctr Mol Design & Synth, Dept Chem, Taejon 305701, South Korea

[2] Korea Adv Inst Sci & Technol, Ctr Mol Design & Synth, Sch Mol Sci, Taejon 305701, South Korea

[3] KRISS, Elect Device Grp, Taejon 305600, South Korea

[4] Soongsil Univ, Dept Chem, Seoul 156743, South Korea

来源：

ADVANCED MATERIALS | 2003年 / 15卷 / 24期

关键词：

D O I：

10.1002/adma.200305562

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enzyme-catalyzed, ring-opening polymerization of biodegradable aliphatic polyesters has successfully been applied to surface-initiated polymerization (see Figure). Using lipase B as a catalyst, a thin film of poly (epsilon-caprolactone) (PCL) and poly(p-dioxanone) (PPDX) on a gold substrate (after a formation of self-assembled monolayers terminating in hydroxyl groups) is formed.

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页码：2063 / +

页数：5

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