Application of a non-ionic amphiphilic maleic diester as polymerizable surfactant in free-radical emulsion polymerization

被引:16
作者
Bui, CO
Lassau, C
Charleux, B
Vairon, JP
Tintiller, P
Le Hen-Ferrenbach, C
机构
[1] Univ Paris 06, Lab Chim Macromol, F-75252 Paris 05, France
[2] Sidobre Sinnova, Grp HENKEL, F-77981 St Fargeau, Ponthierry, France
关键词
D O I
10.1007/s002890050465
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A non ionic amphiphilic maleic diester with a poly(ethylene oxide) hydrophilic chain was used as a copolymerizable surfactant in batch free-radical emulsion polymerizations of styrene and n-butylacrylate. A good stability during the polymerization process was observed together with a high incorporation of the surfactant.
引用
收藏
页码:287 / 294
页数:8
相关论文
共 21 条
[1]   Reactive surfactants in heterophase polymerization .10. Characterization of the surface activity of new polymerizable surfactants derived from maleic anhydride [J].
Abele, S ;
Sjoberg, M ;
Hamaide, T ;
Zicmanis, A ;
Guyot, A .
LANGMUIR, 1997, 13 (02) :176-181
[2]   Reactive surfactants in heterophase polymerization. 11. Particle nucleation [J].
Amalvy, JI ;
Unzue, MJ ;
Schoonbrood, HAS ;
Asua, JM .
MACROMOLECULES, 1998, 31 (17) :5631-5638
[3]  
BRANDRUP J, 1989, POLYM HDB
[4]  
BRIGITTE E, 1984, THESIS U C BERNARD L
[5]  
ELISEEVA SS, 1981, EMULSION POLYM ITS A
[6]   EMULSION COPOLYMERIZATION OF STYRENE WITH MONOMERIC EMULSIFIERS [J].
GOEBEL, KH ;
STAHLER, K .
POLYMERS FOR ADVANCED TECHNOLOGIES, 1995, 6 (07) :452-454
[7]  
Guyot A, 1997, J APPL POLYM SCI, V65, P2289, DOI 10.1002/(SICI)1097-4628(19970919)65:12<2289::AID-APP4>3.3.CO
[8]  
2-8
[9]  
GUYOT A, 1994, ADV POLYM SCI, V111, P43
[10]   SYNTHESIS AND NMR CHARACTERIZATION OF NEW POLY(ETHOXYALKYL) MALEATES - SURFACTANTS FOR EMULSION POLYMERIZATION [J].
HAMAIDE, T ;
ZICMANIS, A ;
MONNET, C ;
GUYOT, A .
POLYMER BULLETIN, 1994, 33 (02) :133-139