Electrochemical synthesis of functionalized nickel oxide nanowires

被引:25
作者
Mintz, TS [1 ]
Bhargava, YV
Thorne, SA
Chopdekar, R
Radmilovic, V
Suzuki, Y
Devine, TM
机构
[1] Univ Calif Berkeley, Dept Mat Sci & Engn, Berkeley, CA 94720 USA
[2] Lawrence Berkeley Natl Lab, Natl Ctr Electron Microscopy, Berkeley, CA 94720 USA
关键词
D O I
10.1149/1.1996511
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Bulk quantities of self-assembled, functionalized nickel oxide nanowires (lengths <= 20 mu m; mean diameter 25 nm) have been grown by a novel electrochemical method consisting of multistep oxidation of Ni-Cr alloys in high-temperature, pressurized water. Nanowires form when growth results in a deficit of OH- in the electrolyte ahead of the growing NiO. The compositional gradient breaks up the planar NiO/water interface into a cellular interface, resulting in the growth of NiO nanowires. (c) 2005 The Electrochemical Society.
引用
收藏
页码:D26 / D30
页数:5
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