A novel pentamanganese(II) cluster produced by a controlled self assembly process; an exact match between the coordination algorithm of the metals and the ligand binding site arrangement

被引：42

作者：

Matthews, CJ

Xu, ZQ

Mandal, SK

Thompson, LK ^{[1
]}

Biradha, K

Poirier, K

Zaworotko, MJ

机构：

[1] Mem Univ Newfoundland, Dept Chem, St John, NF A1B 3X7, Canada

[2] St Marys Univ, Dept Chem, Halifax, NS B3H 3C3, Canada

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 04期

关键词：

D O I：

10.1039/a808970a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tetradentate ligand phaap combines a bridging alkoxide oxygen and diazine and pyridine nitrogen donors, with five critically positioned binding sites, and on reaction with Mn(ClO4)(2). 6H(2)O undergoes a controlled self assembly to produce a unique trigonal bipyramidal oxygen bridged metal cluster with an exact match between the coordination requirements of the five six-coordinate metals and the donor arrangements of the six coordinated ligands.

引用

页码：347 / 348

页数：2

共 12 条

[1] Tetra- and pentamanganese(II) macrocyclic complexes with bridging carboxylate groups: Product control by pretreatment of manganese acetate solutions [J].