Effect of guest capture modes on molecular recognition by a dynamic cavity array at the air-water interface:: soft vs. tight and fast vs. slow

被引:35
作者
Ariga, K
Nakanishi, T
Hill, JP
Terasaka, Y
Sakai, D
Kikuchi, J
机构
[1] Natl Inst Mat Sci, Supermol Grp, Adv Mat Lab, Tsukuba, Ibaraki 3050044, Japan
[2] NIMS, ICYS, Tsukuba, Ibaraki 3050044, Japan
[3] Nara Inst Sci & Technol, Grad Sch Mat Sci, Ikoma 6300192, Japan
关键词
D O I
10.1039/b501945a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Dynamic aspects of molecular recognition at the air-water interface have been investigated using a monolayer of a steroid cyclophane SC(OH) which consists of the rigid 1,6,20,25tetraaza[6.1.6.1]paracyclophane ring, connected to four steroid moieties (cholic acid) through flexible L-lysine spacers. An aqueous fluorescent guest (TNS) can be reversibly captured by SC(OH) with a variation in the accompanying fluorescence emission upon compression and expansion of the SC(OH) monolayer. Tight capture, by compression of the monolayer to a high surface pressure, efficiently enhances fluorescence intensity because of suppression of formation of the non-emissive state. On the other hand, rapid motion of the reversible cavity formation by a high rate of compression and expansion of the monolayer results in better reproducibility in the fluorescence change than that obtained under a slower motion, which can be explained by the suppression of unfavorable structural relaxation within the monolayer structures. This result has connotations for the development of novel molecular devices and machines that operate through mechanically driven molecular recognition.
引用
收藏
页码:132 / 137
页数:6
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