Influence of neutral ligands on the structures of silver(I) sulfonates

被引：159

作者：

Li, FF ^{[1
]}

Ma, JF ^{[1
]}

Song, SY ^{[1
]}

Yang, J ^{[1
]}

Liu, YY ^{[1
]}

Su, ZM ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 25期

关键词：

D O I：

10.1021/ic050984z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This article represents a systematical examination of the structures of silver(I) sulfonates incorporating neutral ligands. To survey the influence of the properties of neutral ligands on the structures of silver(I) sulfonates, three kinds of sulfonate anions (L1 = 1-naphthalenesulfonate, L2 = p-toluenesulfonate, and L3 = 1, 3, 6, 8-pyrenetetrasulfonate) and three kinds of neutral ligands (pyrazine, Pyr, a divergent bidentate ligand; hexamethylenetetramine, hmt, a divergent tetradentate ligand; and P-picoline, Pic, a monodentate ligand) were selected for study, and five novel silver(l) sulfonates containing neutral ligands have been synthesized: [Ag(L1)(Pyr)](H2O)-H-. (1), Ag(L2)(Pyr) (2), Ag-4(L3)(Pyr)(4)(H2O)(2) (3), [Ag(L1)(hmt)](H2O)-H-. (4), and Ag(L1)(PiC)(2) (5). The crystal structures have been determined by single-crystal X-ray diffraction, and these compounds show a variety of structures with different dimensionalities. Moreover, the luminescent properties of compounds 2, 4, and 5 are also discussed.

引用

页码：9374 / 9383

页数：10

共 66 条

[1]

Alberti G, 1996, COMPREHENSIVE SUPRAM, P151

[2] CRYSTAL-STRUCTURE OF SILVER 4-CHLOROBENZENESULFONATE, AG(C6H4SO3CL) [J].

BERNARDINELLI, G ;

LUCKEN, EAC ;

COSTINES, M .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1991, 195 (1-2) :145-146

[3] CRYSTAL-STRUCTURE OF SILVER METHANESULFONATE [J].

CHARBONNIER, F ;

FAURE, R ;

LOISELEUR, H .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (SEP15) :2824-2826

[4] CRYSTAL-STRUCTURE OF SILVER BROMOMETHANESULFONATE [J].

CHARBONNIER, F ;

FAURE, R ;

LOISELEUR, H .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (DEC) :3598-3601

[5] DOUBLE CONFORMATION OF THE METHANE DISULFONATO GROUP WITHIN THE SAME CRYSTAL OF SILVER(I) METHANE DISULFONATE [J].

CHARBONNIER, F ;

FAURE, R ;

LOISELEUR, H .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (AUG) :1773-1775

[6] COORDINATION AND ARRANGEMENT OF SILVER IN CRYSTALLIZED 1,2-ETHANEDISULFONATE AND 1,4 BUTANEDISULFONATE SILVER(I) [J].

CHARBONNIER, F ;

FAURE, R ;

LOISELEUR, H .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1981, 37 (APR) :822-826

[7]

CHARBONNIER F, 1981, CRYST STRUCT COMMUN, V10, P1129

[8] Assembly via H-bonds and Ag-Ag attractions of one-dimensional silver(I) complexes of nicotinamide and nicotinic acid with sulfonate counter-anions [J].

Chen, CH ;

Cai, JW ;

Feng, XL ;

Chen, XM .

POLYHEDRON, 2002, 21 (07) :689-695

[9] Recent advances in metal phosphonate chemistry [J].

Clearfield, A .

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 1996, 1 (02) :268-278

[10]

Clearfield A, 1998, PROG INORG CHEM, V47, P371

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