Nanocomposite materials consisting of alternating layers of molybdenum disulfide and cobalt or nickel hydroxides: Magnetic characterization

被引:11
作者
Golub, AS [1 ]
Payen, C [1 ]
Protzenko, GA [1 ]
Novikov, YN [1 ]
Danot, M [1 ]
机构
[1] RUSSIAN ACAD SCI,INST ORGANOELEMENT CPDS,MOSCOW 117813,RUSSIA
基金
俄罗斯基础研究基金会;
关键词
nanostructures; chemical synthesis;
D O I
10.1016/S0038-1098(97)00015-X
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Magnetization measurements were performed from 5 to 300 K on nanocomposite compounds obtained by precipitation of MoS2 single-layer dispersion in the presence of Co2+ or Ni2+ ions. Ni(II) and high spin Co(II) were evidenced, both in octahedral oxygen surrounding. From similarity of their temperature magnetic behavior with that of lamellar references Ni(OH)(2) and beta-Co(OH)(2) powders, it can be inferred that the nanocomposites contain 2D nickel or cobalt hydroxide species. The low temperature magnetic behavior is discussed on the basis of dimensionality and finite particle size effects. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:419 / 423
页数:5
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