The high fifth-order nonlinearity in a new stilbazolium derivative:: trans-1-[p-(p-dimethylaminobenzyl-azo)-benzyl]2-(N-methyl-4-pyridinium)-ethene iodide

被引:28
作者
Zhan, CL [1 ]
Li, DH
Wang, DY
Zhang, DQ
Li, YJ
Xu, W
Lu, ZZ
Zhao, LZ
Nie, YX
Zhu, DB
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Organ Solids Lab, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Photochem, Beijing 100080, Peoples R China
[3] Chinese Acad Sci, Inst Phys, Lab Opt Phys, Beijing 100080, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1016/S0009-2614(01)01059-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The third- and fifth-order optical nonlinearities from the titled molecule were investigated using Z-scan technique. The titled molecule exhibits two-photon absorption (2PA) and 2PA-generated excited-state absorption (ESA). A very interesting feature is that the titled molecule shows a high fifth-order nonlinearity, being about one-order of magnitude larger than the reported organic molecules. Due to this strong ESA, a highly efficient optical limiting effect was observed. (C) 2001 Elsevier Science BN. All rights reserved.
引用
收藏
页码:410 / 414
页数:5
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