Fragmentation of ionized liquid helium droplets:: A new interpretation

被引:84
作者
Callicoatt, BE [1 ]
Förde, K
Jung, LF
Ruchti, T
Janda, KC
机构
[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
[2] Univ Calif Irvine, Inst Surface & Interface Sci, Irvine, CA 92697 USA
关键词
D O I
10.1063/1.477713
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Pure liquid helium droplets of mean size [N] = 100-15000 atoms ionized by electron impact show surprisingly similar ion fragment distributions. For all cluster sizes He-2(+) is the most probable cluster ion fragment, accounting for 30%-70% of the total ion yield. The high relative intensity of He-2(+) for the larger clusters shows that the droplets dissipate the ionization energy through an impulsive process, which ejects He-2(+) from me cluster, rather man by thermal evaporation. The other helium ion fragments that have been the focus of previous studies ate most likely formed by a similar mechanism. (C) 1998 American Institute of Physics. [S0021-9606(98)00547-9].
引用
收藏
页码:10195 / 10200
页数:6
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