Electron attachment cross sections and negative ion states of SF6

被引:76
作者
Christophorou, LG [1 ]
Olthoff, JK [1 ]
机构
[1] Natl Inst Stand & Technol, Div Elect, Elect & Elect Engn Lab, Gaithersburg, MD 20899 USA
关键词
cross sections; electron attachment; negative ions; SF6; sulfur hexafluoride;
D O I
10.1016/S1387-3806(00)00280-3
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
A comprehensive and critical assessment of published data on the total, dissociative and nondissociative electron attachment cross sections for SF6 allowed us to recommend or suggest room temperature values for these cross sections over an energy range from 0.0001 eV to 15 eV. The total electron attachment cross section is dominated by the formation of SF6- below similar to0.2 eV, by the formation of SF; between similar to0.3 eV and 1.5 eV, and by the formation of F- beyond similar to2.0 eV. This work, along with electron scattering and theoretical data, allowed us also to identify the energies and symmetry assignments of the negative ion states of SF6 below similar to 15 eV. (C) 2001 Elsevier Science B.V.
引用
收藏
页码:27 / 41
页数:15
相关论文
共 109 条
[1]   HIGH-RESOLUTION THRESHOLD PHOTOELECTRON-SPECTROSCOPY BY ELECTRON-ATTACHMENT [J].
AJELLO, JM ;
CHUTJIAN, A .
JOURNAL OF CHEMICAL PHYSICS, 1976, 65 (12) :5524-5525
[2]   ATTACHMENT TO SF6 OF ELECTRONS BOUND IN RYDBERG ATOMS, AUTODETACHMENT AND DISSOCIATION OF SF6- [J].
ASTRUC, JP ;
BARBE, R ;
SCHERMANN, JP .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1979, 12 (12) :L377-L381
[3]   ELECTRON CAPTURE + IONIZATION PHENONEMENA IN SF6 + C7F14 [J].
ASUNDI, RK ;
CRAGGS, JD .
PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1964, 83 (5344) :611-&
[4]   TOTAL CROSS-SECTION OF SF6 MOLECULE FOR ELASTIC ELECTRON-SCATTERING [J].
BENEDICT, MG ;
GYEMANT, I .
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 1978, 13 (05) :597-603
[5]  
BETEROV IM, 1987, Z PHYS D, V6, P55
[6]  
BUCHELNIKOVA IS, 1959, SOV PHYS JETP-USSR, V8, P783
[7]   OBSERVATION OF L-DEPENDENT RATE CONSTANTS FOR ION PRODUCTION IN RYDBERG ELECTRON-TRANSFER REACTIONS [J].
CARMAN, HS ;
KLOTS, CE ;
COMPTON, RN .
JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (05) :2580-2584
[8]   PHOTON-ENHANCED DISSOCIATIVE ELECTRON-ATTACHMENT IN SF6 AND ITS ISOTOPIC SELECTIVITY [J].
CHEN, CL ;
CHANTRY, PJ .
JOURNAL OF CHEMICAL PHYSICS, 1979, 71 (10) :3897-3907
[9]   DETERMINATION OF THE ELECTRON-AFFINITIES OF MOLECULES USING NEGATIVE-ION MASS-SPECTROMETRY [J].
CHEN, ECM ;
WILEY, JR ;
BATTEN, CF ;
WENTWORTH, WE .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (01) :88-94
[10]   THE NEGATIVE-ION STATES OF SULFUR-HEXAFLUORIDE [J].
CHEN, ECM ;
SHUIE, LR ;
DSA, ED ;
BATTEN, CF ;
WENTWORTH, WE .
JOURNAL OF CHEMICAL PHYSICS, 1988, 88 (08) :4711-4719