Molecular miscibility characteristics of self-assembled 2D molecular architectures

被引：30

作者：

Ma, Xiaojing ^{[1
]}

Yang, Yanlian ^{[1
]}

Deng, Ke ^{[1
]}

Zeng, Qingdao ^{[1
]}

Zhao, Keqing ^{[2
]}

Wang, Chen ^{[1
]}

Bai, Chunli ^{[1
]}

机构：

[1] Natl Ctr Nanosci & Technol, Beijing 100080, Peoples R China

[2] Sichuan Normal Univ, Dept Chem, Chengdu 610066, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2008年 / 18卷 / 18期

关键词：

D O I：

10.1039/b713426f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Various molecular networks, stabilized by hydrogen bonds or van der Waals interactions, are demonstrated in which the distribution of heterogeneous molecular species could be controlled at the level of single molecules or molecular clusters. The observed miscibility characteristics of the two-dimensional (2D) assembly structures could enable studies on the heterogeneous molecular interfaces of guest-host architectures. In addition, it could be envisioned that large cavity networks should be beneficial for studying the clustering behavior of molecular aggregates of similar or dissimilar species, chemical interactions in nanometre scale constrained areas, as well as the design of complex molecular architectures.

引用

页码：2074 / 2081

页数：8

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