Viscosity at small scales in polymer melts

被引:202
作者
Wyart, FB
de Gennes, PG
机构
[1] Inst Curie, PSI, F-75231 Paris 05, France
[2] Coll France, F-75231 Paris 05, France
关键词
D O I
10.1007/s101890050011
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Flows around small colloidal particles of diameter b, or in thin films, capillaries, etc., cannot always be described in terms of the macroscopic polymer viscosity. We discuss these features for entangled polymer melts! where two distinct regimes can be found: (a) the thin regime where b is smaller than the coil radius R-0, but larger than the diameter d(t) of the Edwards tube; (b) the ultrathin regime, where b < d(t). We consider (i) non adsorbing particles, where slippage may occur between the melt and the solid surface; (ii) ''hairy" particles, which carry some bound polymer chains. We obtain scaling predictions for mobilities of spheres, of needles, and of clusters of particles. We also discuss translational and rotational diffusion of needles.
引用
收藏
页码:93 / 97
页数:5
相关论文
共 12 条
[1]   SHEAR-DEPENDENT SLIPPAGE AT A POLYMER SOLID INTERFACE [J].
BROCHARD, F ;
DEGENNES, PG .
LANGMUIR, 1992, 8 (12) :3033-3037
[2]  
BROCHARD F, 1984, J PHYS LETT-PARIS, V45, pL597, DOI 10.1051/jphyslet:019840045012059700
[3]   Slippage of polymer melts on grafted surfaces [J].
BrochardWyart, F ;
Gay, C ;
deGennes, PG .
MACROMOLECULES, 1996, 29 (01) :377-382
[4]  
DEGENNES PG, 1970, PHYS KONDENS MATER, V11, P189
[5]   MOTIONS OF ONE STIFF MOLECULE IN AN ENTANGLED POLYMER MELT [J].
DEGENNES, PG .
JOURNAL DE PHYSIQUE, 1981, 42 (03) :473-477
[6]  
DEGENNES PG, 1979, CR ACAD SCI B PHYS, V289, P265
[7]   WETTING - STATICS AND DYNAMICS [J].
DEGENNES, PG .
REVIEWS OF MODERN PHYSICS, 1985, 57 (03) :827-863
[8]  
Doi M., 1986, The Theory of Polymer Dynamics
[9]  
Gennes P.-G., 1990, INTRO POLYM DYNAMICS
[10]   SEDIMENTATION OF LARGE COLLOIDAL PARTICLES THROUGH SEMIDILUTE POLYMER-SOLUTIONS [J].
LANGEVIN, D ;
RONDELEZ, F .
POLYMER, 1978, 19 (08) :875-882