Structure and thermal properties of blends of nylon 6 and a liquid crystal copolyester

被引:125
作者
Campoy, I [1 ]
Gomez, MA [1 ]
Marco, C [1 ]
机构
[1] CSIC, Inst Ciencia & Tecnol Polimeros, E-28006 Madrid, Spain
关键词
nylon; 6; Vectra; blends;
D O I
10.1016/S0032-3861(98)00181-5
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Blends of nylon 6 with the liquid crystal copolyester Vectra have been prepared from the melt with different compositions, and their thermal behaviour has been analysed by differential scanning calorimetry (d.s.c.) and Xray diffraction (WAXS) using syncrotron radiation, as a function of temperature and thermal treatment. The structural properties of these blends have been found to be very sensitive to the thermal history, and particular attention has been paid to the effect of the liquid crystal content in the polymorphic transformations of nylon 6. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:6279 / 6288
页数:10
相关论文
共 45 条
[1]  
ACIERNO A, 1993, PROCESSING PROPERTIE
[2]   ALPHA-GAMMA TRANSITION OF NYLON 6 [J].
ARIMOTO, H .
JOURNAL OF POLYMER SCIENCE PART A-GENERAL PAPERS, 1964, 2 (5PA) :2283-&
[3]  
ARIMOTO H, 1965, J POLYM SCI, pA3
[4]  
BEERY D, 1991, POLYM ENG SCI, V31, P451, DOI 10.1002/pen.760310612
[5]   STRUCTURE AND PROPERTIES OF MOLDED POLYBLENDS CONTAINING LIQUID-CRYSTALLINE POLYMERS [J].
BEERY, D ;
KENIG, S ;
SIEGMANN, A .
POLYMER ENGINEERING AND SCIENCE, 1991, 31 (06) :459-466
[6]  
BRAUNPDRUP J, 1989, POLYM HDB
[7]   CRYSTALLIZATION KINETICS OF POLYPROPYLENE-POLYAMIDE COMPATIBILIZED BLENDS [J].
CAMPOY, I ;
ARRIBAS, JM ;
ZAPORTA, MAM ;
MARCO, C ;
GOMEZ, MA ;
FATOU, JG .
EUROPEAN POLYMER JOURNAL, 1995, 31 (05) :475-480
[8]  
CAMPOY I, 1998, J THERM ANAL, V52, P1
[9]  
ChangChien GP, 1996, POLYM ADVAN TECHNOL, V7, P168, DOI 10.1002/(SICI)1099-1581(199603)7:3<168::AID-PAT531>3.0.CO
[10]  
2-H