In situ NMR analysis of fluids contained in sedimentary rock

被引：28

作者：

de Swiet, TM ^{[1
]}

Tomaselli, M

Hürlimann, MD

Pines, A

机构：

[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA

[2] Schlumberger Doll Res Ctr, Ridgefield, CT 06877 USA

[3] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

JOURNAL OF MAGNETIC RESONANCE | 1998年 / 133卷 / 02期

关键词：

NMR; porous media; rocks; oil; MAS;

D O I：

10.1006/jmre.1998.1459

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Limitations of resolution and absorption in standard chemical spectroscopic techniques have made it difficult to study fluids in sedimentary rocks. In this paper, we show that a chemical characterization of pore fluids may be obtained in situ by magic angle spinning (MAS) nuclear magnetic resonance (NMR), which is normally used for solid samples. H-1 MAS-NMR spectra of water and crude oil in Berea sandstone show sufficient chemical shift resolution for a straightforward determination of the oil/water ratio, (C) 1998 Academic Press.

引用

页码：385 / 387

页数：3

共 23 条

[1]

AMYX J W, 1988, Petroleum Reservoir Engineering

[2] ANALYTICAL TECHNIQUES IN COMBINATORIAL CHEMISTRY - MAS CH CORRELATION IN SOLVENT-SWOLLEN RESIN [J].

ANDERSON, RC ;

JAREMA, MA ;

SHAPIRO, MJ ;

STOKES, JP ;

ZILIOX, M .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (09) :2650-2651

[3] NUCLEAR MAGNETIC RESONANCE IN DIAMAGNETIC MATERIALS - POSSIBILITIES FOR HIGH-RESOLUTION NUCLEAR MAGNETIC RESONANCE SPECTRA OF CRYSTALS [J].

ANDREW, ER ;

EADES, RG .

DISCUSSIONS OF THE FARADAY SOCIETY, 1962, (34) :38-+

[4]

Bear J., 1998, Dynamics of Fluids in Porous Media. Civil and Mechanical Engineering

[5] MICROSCOPIC ARRANGEMENT OF OIL AND WATER IN SANDSTONE BY NMR RELAXATION-TIMES AND NMR IMAGING [J].

BOBROFF, S ;

GUILLOT, G ;

RIVIERE, C ;

CUIEC, L ;

ROUSSEL, JC ;

KASSAB, G .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1995, 92 (10) :1885-1889

[6]

Callaghan P.T., 1991, Principles of nuclear magnetic resonance microscopy, V1st

[7] QUANTIFICATION OF OIL AND WATER IN PRESERVED RESERVOIR ROCK BY NMR-SPECTROSCOPY AND IMAGING [J].

DAVIES, S ;

HARDWICK, A ;

ROBERTS, D ;

SPOWAGE, K ;

PACKER, KJ .

MAGNETIC RESONANCE IMAGING, 1994, 12 (02) :349-353

[8] EFFECTS OF MACROSCOPIC SPINNING UPON LINEWIDTH OF NMR SIGNALS OF LIQUID IN MAGNETICALLY INHOMOGENEOUS SYSTEMS [J].

DOSKOCILOVA, D ;

TAO, DD ;

SCHNEIDER, B .

CZECHOSLOVAK JOURNAL OF PHYSICS, 1975, B 25 (02) :202-209

[9]

Ernst R. R., 1987, PRINCIPLES NUCL MAGN

[10] HIGH-RESOLUTION CHEMICAL-SHIFT AND CHEMICAL-SHIFT ANISOTROPY CORRELATION IN SOLIDS USING SLOW MAGIC ANGLE SPINNING [J].

GAN, ZH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (21) :8307-8309

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